Ink jet make-up applicator

WO 2015/097618 A2
Transfer makeup process and related device
L’Oreal

This patent application describes a process that L’Oreal have used to demonstrate transfer printing of makeup onto a human body. If a transfer process is used for makeup then it is desirable that the materials are still moist at the time of transfer and shortly after, so that the transfer process is successful and that any retouching or blending can take place after transfer.

Jul-15aA Canon Pixma IP100 printer was modified so that instead of feeding paper the mechanism would rotate a transfer roller. Inks were prepared according to the table below.

The transfer roller had a diameter 60 mm and length of 80 mm with a blanket surface 2 mm thick, made from a silicone gel elastomer.

Jul-15bAfter printing the transfer roller 1 is rolled along the appropriate body part transferring the makeup or image. A variety of different profile rollers are proposed, flat for backs and other body areas, and concave for arms and legs. For smaller parts of the body such as lips and eyelids then pads using the transfer material would be used.

High solids content ink for intermediate transfer

US 2015/0175821 A1
EP 2 886 618 A1
US 2015/0175820 A1
Aqueous dispersible siloxane-containing polymer inks useful for printing
Xerox Corporation

Aqueous indirect printing technology, in which an intermediate transfer member (ITM) is used to transfer the ink jet printed image to the target media, is currently of great interest and is generating numerous patents by a number of key players.

These Xerox patents take an interesting approach in that they focus solely on the polymer chemistry of the binder and then its interaction with the ITM surface. Firstly, the patent suggests that aqueous inks are preferred not just from an environmental perspective, but because they do not attack the ITM hydrophobic surface. It seems that this is especially true if the hydrophobic belt is treated with a release fluid similar to the dampening fluid used in lithographic printing, in this case suggested to be octamethylcyclotetrasiloxane.

In particular, the patent proposes the synthesis of a siloxane containing polymer dispersion to enable the efficient wetting of such a hydrophobic surface without having to use separate wetting agents, which apparently could swell and interfere with the dampening fluid and/or belt surface, causing print transfer issues. The polymer of interest is a self dispersing sulfonated polyestersiloxane, the core of which is similar to the excellent Eastman Eastek series of polymer dispersions. The benefit of such self dispersing polymers is that they contain essentially no surfactant and their inherent stability generally results in low viscosity dispersions of very low particle size.

The exemplified polymer was prepared by taking dimethylterephthalate (313g), sodium dimethyl 5-sulfoisophthalate (38g) 1,2-propane diol (250g), diethyleneglycol (37.5g), polydimethylsiloxane carbomethoxy terminated and butyl tin oxide (1g) as catalyst and were charged into a suitable one litre reaction vessel and heated to 175C for 1 hour, increasing to 185C for a further 3 hours, all the while removing the methanol and water by-product from the mixture as the polymerisation progressed. The vessel was finally taken to 200C and put under reduced pressure for 2 hours to remove excess glycol. The resultant polymer was discharged whilst still molten to give a polymer with a Tg of 55.2C, a number average molecular weight (Mn) of 2237g/mol and a weight average molecular weight (Mw) of 3777 g/mol. The polymer structure is shown in the diagram below, with n:m:X:p ratios of 1.00 : 0.86 : 0.61 : 1.090.

June-15
To prepare the ink, first a cyan (15 wt% pigment) dispersion in water was prepared containing a Dowfax surfactant as dispersant. 100g of this was heated to 80C and15g of the above resin was added, stirred for 1 hour and then allowed to cool to room temperature. This resulted in a blue ink with total solids of 27% and with a suggested viscosity of <10cps.

No ink jet printing is discussed, but the manual coating on to a treated hydrophobic transfer surface and then on to the media is discussed and it is suggested that the siloxane component is critical in formulations without aggressive wetting agents. An additional benefit of these self dispersing polymer dispersions is suggested to be the exceptionally high solids loading achievable for ink jet printable formulations. This is important as little water is apparently needed to significantly raise the viscosity to levels suitable for transfer to the media. What this means for the printhead dwell time is not discussed.

Landa Digital update

WO 2015/036906 A1
Digital printing system
Landa Corporation Ltd.

In March/April 2015 another batch of patents covering the new technology being developed by Landa Digital were published. With a filing date of just 4 months after the first batch the changes are small, but still possibly significant. Here we review one concerning the intermediate transfer belt.

The Landa process is designed to produce high quality images on any existing commercial print papers using aqueous inks. To do this, images are formed on an intermediate transfer belt, dried and then transferred to the final substrate. The belt has a silicone rubber surface to give excellent release properties of the image to the final substrate. However that also means it is non-wetting to the inks which if nothing is done would bead and coalesce on the belt surface leading to very poor image quality. To solve this the belt is coated with a conditioning fluid just prior to the imaging station. The conditioning fluid freezes the drops in the flat round ‘impact’ form long enough for sufficient water to be removed, hence increasing the drop viscosity and immobilising it on the belt.

Mar-15
The figure shows a section through the imaging and transfer systems. Belt 102 passes through the cleaning and conditioning station 120 where any residual ink is removed and the conditioning fluid is applied ready for the next cycle. The belt then passes under printheads 106 which have hot air blowers 130 between each of them. These stabilise the drops by removing enough of the water to keep them in their ‘impact’ shape. The image then passes under drying station 108 where the drops are dried and rendered tacky ready for the transfer stage.

There are two transfer stations, and the substrate can be flipped in between them allowing duplex printing to take place. Before each transfer step dryers 210 can reheat the image, making it tacky again for transfer.

This patent application proposes that the belt be thinner than previously proposed. The thicker belt combined a compliant layer or blanket with the belt itself. The conformal layer is required to ensure that the image conforms to the surface structure of the substrate. Unfortunately the belt has been found to wear out despite the blanket having a greater working life.

The thin belt is paired with a compression layer on the pressure cylinders 110a and 110a’. The thin belt still has a conformal layer, between 100-400 microns, with the cylinder conformal layer much thicker at 2.5 mm. Using a thinner belt has several other advantages apart from increased life. There is a large reduction in mass and therefore the energy required to move it. The thermal inertia is also much lower, meaning that the time and energy required to heat it and cool it is reduced. Even so it seems that residual heat can build up in the belt, so the conditioning unit 120 can also be used to cool the belt.

Intermediate transfer technology from Xerox

US 2015/0022605 A1
System and method for transfixing an aqueous ink in an image transfer system
EP 2 826 633 A1
System and method for transfixing an aqueous ink in an image transfer system
Xerox Corporation

Interest in intermediate transfer systems is high at present, no doubt as a result of the Landa Digital demonstrations at Drupa 2012. Xerox has for many years sold printers using intermediate transfer methods with phase change inks. But the goal here is to find a way of doing the same with liquid inks. It is also desirable to not involve heat for the transfer process if possible, as excessive temperature of the transfer substrate will shorten its life.

The intermediate transfer substrate needs to have properties that will allow the release of the ink film and its transfer to the substrate, yet the ink must wet it sufficiently on landing. Insufficient wetting results in ‘drawback’; at impact the drop is flattened, but then surface tension pulls the ink back into a drop.

The proposed solution is to coat the intermediate transfer substrate with a powder layer including an aggregation treatment agent capable of precipitating colorants, latex or resin in the ink drops.

Jan-15The particles are very small, 1-10 microns in diameter, and need to be coated uniformly and at uniform density on the substrate. Coverage of 5-40% is sufficient providing the particle distribution is uniform, so that many particles will be impacted by an individual drop.

Not surprisingly, considering Xerox’ background, methods of coating the powder include electrostatically biased rollers, brushes, and cloud development used in electrophotography. The particles contained metal salts, such as iron sulphate and copper sulphate. These are combined with other materials to form the powder.

As the drops impact the powder the colorant or pigment begins to precipitate out of the ink due to the aggregation agent in the particles. As the process continues a coating of pigment and resin is formed on the substrate surface. This causes further diffusion of the aggregation agent into the drop, and also prevents the drawback of the ink. Examples shown and discussed in the patent use 14 pl drops printed on to a silicon plate as the substrate.

Inside Landa’s Nanography process

WO 2013/132418 A2
Digital printing process
Landa Corporation Limited

This patent application describes the complete process and makes the basic claims for the overall process.  The first drawing is a schematic and is not to scale.  Multiple array printheads 300 print an image on to a heated intermediate substrate belt 130 which rotates clockwise around rollers 104 and 106.  The image dries partly due to the heated belt but with additional heating from above (not shown).  The printheads can be moved backwards from the belt to maintenance and capping stations.

Sheets are fed from a conventional offset press sheet feeder 506 and are transported through the machine by a series of gripper drums.  Drums 502 and 504 bring the substrate into contact with the image on the belt, transfer being enabled by pressure from back-up rollers 140 and 142.  After the first side of the sheet has been printed at the first impression, it is passed by a further gripper drum to the perfecting cylinder 524.  The perfecting cylinder has a circumference twice that of the other drums.  The grippers are timed so that as the trailing edge passes drum 526 the grippers grab the rear edge.  At the second impression stage the back side of the sheet is then printed.  In this way the single imaging engine can be used to print duplex.  To do this the images for Sep13-2
each side of the sheet are formed alternately and mirror-imaged so that after transfer they are correctly orientated.

After transfer to the sheet, the ink is dry enough to be handled by the gripper drums and the output stacker 508.  No further curing or drying of the image is required.

Other configurations are possible, and in fact a simplex web press was shown at Drupa 2012.  There is just one impression cylinder and pressure roller pair 502 and 140.  To ensure none of the web substrate is wasted, it’s fed intermittently past the impression cylinder to close up any gaps between the images on the transfer belt.  As the web drive has considerable momentum, the intermediate feed is achieved by using dancer rollers 554 and 556.

Going back to the duplex sheet-fed press, the figure below shows the intermediate substrate or blanket support system with the blanket and front support removed.   The roller 104 serves to pull the belt past the printheads at a constant speed, while roller 106 is also driven but is adjusted to keep the belt in a state of constant tension across the top run.  Roller 104 is mounted in pillow blocks so that it can be moved to allow for belt stretch.  Pressure rollers 140 and 142 are mounted inside the support, press against the blanket at the transfer points to the substrate, and can be raised and lowered.

Sep13-3
The blanket runs in contact with thermally conductive support plates 130.  The junctions between these plates are deliberately staggered to prevent the creation of a line along the belt.  Heater elements 132 under the plates supply the heat to the belt along the upper run.

Not shown is a fan system to create a negative air pressure within the blanket support box.  This helps keep the blanket in contact with the heated plates, and also keeps the bottom run of the blanket from contacting the impression cylinders when the pressure rollers are withdrawn.

Each of the sides of the blanket support has a track 180 which engages in features fixed to the sides of the blanket.  This serves two purposes.  Firstly it enables the blanket to be threaded through the machine by entering it into the guides.  Although the blanket could be made as an endless belt, it is more economical to make it as a sheet and join the ends within the machine.  Secondly it steers the belt past the printheads and maintains tension across the belt.

Sep13-4
To the left is a top view of belt 210.  Alongside each side are features 270.  These can be one half of a zip fastener that has been sewn to the edges of the blanket.  The projections 270 are contained within the channel of track 280.  Roller bearings 282 can be used to reduce the friction.  As the belt is heated the components must be capable of withstanding up to 250C.  Suitable materials for the projections include a polyamide reinforced with molybdenum disulphide.  The guides are used to stabilise and tension the belt as it passes the printheads to ensure accurate image formation, but can be omitted through the drying station and in other places where the belt is slack.

Sep13-5
The blanket is formed into a continuous belt using a zip or hooks and loops fastener.  This may be supplemented by adhesive or tape.  It is important that the seam is the same thickness as the belt itself, otherwise there will be speed variations when the seam passes over the driven rollers.

Details of the ink can be found in Directions September/October 2013 page 17, and materials and structure of the blanket in the media reviews in this issue of Direction on page 22.  The surface of the blanket has a thin upper release layer that is hydrophobic, such as a silicone material.  This is formed on a reinforcement layer, such as a fabric.

A pre-treatment liquid can be applied to the blanket by a roller mounted opposite tension roller 106.  This coats the blanket with a thin dilute film of charged polymer to modify the surface properties.  By the time the blanket reaches the printheads the film is completely dry.

The purpose of this chemical treatment is to counteract the surface tension of the aqueous ink when it contacts the hydrophobic release layer of the blanket.  Without the pre-treatment the drops would flatten on the blanket surface on impact, and then surface tension forces would restore the ink into drops or beads.  With the pre-treatment the negatively charged polymer particles in the ink drop adjacent to the surface are attracted by the positively charged pre-treatment film.  This “freezes” the drop after impact so that beading does not occur.  The effect is very short-lived but long enough for the water to be dried out of the image without the drops coalescing, beading or otherwise disrupting the image.

The blanket is heated from below to around 150C.  In addition, after the print station external air blowers pass hot air over the image to further aid drying.  The polymers in the ink remain tacky at this temperature, aiding the transfer process.

There are many claimed advantages to this process.  First of all, it uses aqueous-based inks which are environmentally friendly, and compared to UV-curable inks use relatively low-cost materials.

The freezing of the ink drops on the blanket enables very thin image layers to be produced, typically 500-800 nm.  This means the image takes up the surface features of the substrate, so that an image on a glossy surface will be glossy, and matt on a matt surface, matching the non-image areas.

When the drops are flattened on impact with the blanket and then frozen they retain the shape formed on impact, hopefully circular.  There is no irregular bleed that is sometimes encountered with direct ink jet printing.  In addition inter-colour bleed is also reduced.

The transferred thin film is less likely to split compared to thicker films, reducing the chances of ink being retained on the blanket and thus requiring cleaning.

Mimaki’s ink jet pad printer

EP 2 546 058 A1
Imaging device and imaging method
Mimaki Engineering Co., Ltd.

Here Mimaki seeks to replace the pad printing processes that are widely used in industry for printing and decorating products.  With pad printing a master plate is formed by etching the image.  The plate is inked and an elastic pad, normally made from silicone rubber, contacts the plate and picks up the ink image.  The pad then presses against the object to be printed transferring the image.  The ink is then dried or cured and the process repeated for the next object.  Although the process works well, the major drawback is that the image is fixed and it takes time and expense to change to a new design.

Jan13The proposed process uses an ink jet printhead 2 to print UV-curable ink on to a transfer sheet 6.  The transfer sheet is thin silicone rubber stretched within a circular metal holder 7.  After printing the ink is partially cured by UV lamp 3.  This raises the ink viscosity from 3-20 cP to 30-300 cP, so the image ends up as a soft paste.

The transfer sheet then passes to the next part of the machine A2.  Here the object to be printed M is pressed against the transfer sheet, which stretches and wraps around the surface, aided by the flexible pad 10.  Almost all of the ink is transferred to the object.  Although the printed object is shown here as a sphere it can of course be any shape.

In the next part of the machine A3 the image on the object is fully cured with UV lamp 11.  If need be the lamp can be moved around the object to ensure all of the image is exposed to the UV radiation.

Finally at section A4 the transfer sheet is cleaned for re-use.  Pads 10 and 12 above and below the transfer sheet press cleaning web 12b against the upper surface to clean any un-transferred ink.